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An important means for monitoring the moving direction of industrial explosives decreases the harms of public. The basis is the product labeling and identification. A RFID- and Barcode- based hybrid mode for information labeling and recognition is proposed in this paper. In the pattern, the barcode is used as the single labeling, and the RFID is used as the batch labeling. A RFID-based information acquiring model and information acquiring technology are represented by means of the Globe class standard and LDAP. The practical application shows that the proposed pattern employs the characteristic of RFID technology which is of far distance, many tags, and large capacity, as well as the advantage which is of barcode’s low cost and to be compatible to the legacy system. The model is constructed between the Bar code and the RFID tag, and the identified accuracy is reached up to 100%. 